Chemical Cleaning of Plate Heat Exchangers: Process, Agents and Field Practice

tech4/8/2025
Chemical Cleaning of Plate Heat Exchangers: Process, Agents and Field Practice

Why Chemical Cleaning Matters

Once fouled, a PHE loses heat-transfer coefficient far faster than a shell-and-tube unit — 30% drops within 3-6 months are common, shown as rising pressure drop, shrinking temperature approach and higher energy cost. Chemical cleaning restores performance with minimal downtime.

Pre-Cleaning Preparation

70% of cleaning success is upfront investigation:

  • Service history and fouling trend
  • Plate and gasket materials (sets the chemical boundary)
  • Scale composition (XRD + chemical analysis)

  • Fouling distribution — uniform or flow-maldistribution zones
  • Bench-scale dissolution test on real scale samples

Standard 7-Step Process

  1. Water flush
  2. Alkaline wash — 85°C, <0.3 m/s, 10-24h, removes organics
  3. Post-alkali rinse to pH≤9
  4. Acid wash — the core descaling step
  5. Post-acid rinse
  6. Rinse — citric/phosphoric acid chelates residual Fe ions
  7. Neutralisation & passivation — forms protective film
Scale TypeMain AgentTemp
Carbonate (most common)HCl 5-8% or sulphamic acidambient-40°C
SulphateEDTA / organic acids80-90°C
Iron oxideHCl + trace HF40-50°C
SilicateCaustic boil + HF90°C / 40°C

Case Study: Alumina PHE at an Aluminium Plant

Stainless-steel detachable PHE with two-layer scale: surface carbonate (easy) and bottom alumina (hard). Only hot concentrated nitric acid dissolved the bottom layer. The "circulate + soak" route ran 12h at controlled velocity; corrosion rate 0.97 g/(m²·h) — well under the 6 g/(m²·h) safety limit; 100% descaling. Waste was neutralised with lime to meet GB 8978-1996.

Welded PHEs: Online Circulation Only

  • Keep velocity under 0.5-0.6 m/s to preserve inhibitor effectiveness
  • Add stabilisers to suspend particulate scale
  • Best for soluble scales; limited on process-side organics

The SAMIT Service Standard

  1. No job without a bench-scale dissolution test
  2. Material-agent compatibility check for plates AND gaskets
  3. Real-time corrosion coupon monitoring; halt on threshold breach

If your PHE shows rising ΔP or shrinking ΔT, contact SAMIT for a free scale-sample evaluation.